GHG quantification
Calculations of GHG emissions for the baseline and project scenarios shall follow a robust, recognized method and good practice guidance. The overall methodological approach is a comparative life cycle assessment (LCA) at the project-scale, based on ISO 14064-2:2019.
This methodology shall be used in conjunction with the Rainbow modules listed below. Modules are like mini-methodologies that only cover a part of the project life-cycle. Combining the relevant modules for a project results in a complete picture of the required data, calculations, monitoring plans, and other information needed for a full GHG quantification.
GHG quantification shall be done separately for each biochar Production Batch, since each batch by definition has distinctly measured biochar carbon characteristics. The GHG quantification results of multiple Production Batches may be combined for one monitoring period.
System boundary
The system boundary of this quantification section starts at the procurement of biomass feedstock, and ends at the biochar end of life, after accounting for decay and re-emission in its end use application. Biomass feedstock production impacts are excluded because biomass is required to be waste or invasive species, and therefore not allocated any production or cultivation emissions. The system boundary includes the following key steps, also displayed in Figure 1:
biomass collection
biomass transport to the kiln
biomass processing (including but not limited to drying and chipping)
energy used to start the kiln (including high-quality wood, and any associated leakage emissions)
energy used to combust methane emissions within the reactor
embodied emissions from manufacturing the kilns, including their shipping to the pyrolysis site and end of life waste treatment
methane emissions from the pyrolysis process
biochar transport to the site of use

Any steps that are fully manual do not incur any GHG emissions. Any steps that would have occurred anyway in the baseline scenario shall be excluded from the system boundary.
The following high-level equations shall be used to calculate carbon removals from distributed biochar projects.
Functional unit
The functional unit shall be 1 tonne of biochar produced or 1 m3 of biochar produced, depending on the project's chosen measurement method for the Biochar amount produced.
Input data shall be provided for all processes related to biochar production in the given Production Batch, and net project removals are first calculated for all processes across the entire duration of the Production Batch.
This is normalized to net removals per functional unit by dividing by the amount of biochar produced in the Production Batch.
The number of credits to issue in the given monitoring period is calculated by multiplying the amount of biochar delivered applied in an eligible end use, by the net removals per tonne or m3 of biochar produced.
This approach is detailed in Eq. 3 above.
Data sources
The required primary data for GHG calculations from projects are presented in Table 1. These data shall be aggregated for all kiln runs within a Production Batch, after being measured and reported in dMRV at the frequencies summarized in the Monitoring section, and made publicly available.
Note that the table does not include all information needed for project monitoring and verification: only the data inputs for ongoing GHG quantification. The full list of information is provided in the minimum requirements for a Monitoring Plan.
Table 1 Summary of primary data needed from projects and their source for GHG quantification. All primary data sources listed here are required to be monitored and updated during verification. *Note that only one approach is required for reporting transport data. See the Transportation module for more details. **See the Infrastructure and machinery module for more details.
General, credit issuance
Volume or mass of biochar delivered in permanent end use
m3 or tonnes of biochar
Measured onsite, dMRV
Carbon storage
Volume or mass of biochar produced
m3 or tonnes of biochar
Measured onsite, dMRV
Carbon storage
Bulk density of biochar (only if using volume)
tonne of biochar/m3
Measured onsite, dMRV
Carbon storage
Biochar moisture content () (only if using mass)
Percent
Elemental analysis by accredited laboratory
Carbon storage
Biochar
Ratio
Elemental analysis by accredited laboratory
Carbon storage
Biochar organic carbon content
Percent
Elemental analysis by accredited laboratory
Carbon storage
Fraction of distribution measurements above 2% (only if using 1000-year approach)
Fraction
Analysis by accredited laboratory
Carbon storage
Residual organic carbon () (only if using 1000-year approach)
Fraction
Analysis by accredited laboratory
Carbon storage
GPS coordinates of biochar spreading sites (for determining soil temperature)
coordinates
dMRV
Biomass leakage
Carbon sequestration rate (or use default 0.5%)
Percent
Secondary literature, models
Pyrolysis process
Methane emissions rate
g CH4/kg dry biochar
Analyses from accredited independent provider
Pyrolysis process
Energy or wood for starting pyrolysis (amount and type)
MJ, kWh, liters fuel, kg wood
Measured onsite, dMRV
Pyrolysis machinery
Item and material type, material amount,
item lifetime**
kg, tonne, m3
years
e.g. kiln made of 80 kg steel for 5 years
Technical specifications, bill of materials, invoices
Transport of biomass
Distance biomass transported by motorized vehicle*
km
Operational records, conservative justified estimates
Transport of biomass
Weight of biomass transported*
tonne
Operational records, conservative justified estimates
Transport of biomass
Vehicle type for biomass transport*
category
Operational records, conservative justified estimates
Transport of biomass
Fuel quantity consumed for biomass transport*
liters fuel
Operational records, conservative justified estimates
Transport of biochar
Distance biochar transported by motorized vehicle*
km
Operational records, conservative justified estimates
Transport of biochar
Weight of biochar transported*
tonne
Operational records, conservative justified estimates
Transport of biochar
Vehicle type for biochar transport*
category
Operational records, conservative justified estimates
Transport of biochar
Fuel quantity consumed for biochar transport*
liters fuel
Operational records, conservative justified estimates
The ecoinvent database version 3.12 (hereafter referred to as ecoinvent) shall be the main source of emission factors unless otherwise specified. Ecoinvent is preferred because it is traceable, reliable, and well-recognized. The ecoinvent processes selected are detailed in Appendix 1.
No other secondary data sources are used in this methodology.
Assumptions
All biochar from the same Production Batch has the same characteristics (e.g. , ...).
All biochar made from the same feedstock has the same methane emission rate from pyrolysis.
The permanent carbon sequestration rate from biomass leakage, where the alternate fate is being left on the field to decompose, is at least 0.5%.
Baseline scenario
There is no baseline because it is assumed that there is no significant share of the project activity already occurring in business-as-usual. Therefore, the baseline for removal credits is zero and is omitted from calculations.
According to the Rainbow Standard Rules, this assumption shall be re-assessed at a minimum every 5 years, and any changes to this assumption would be applied to existing projects.
Project scenario
Biomass leakage
Project leakage shall account for permanent carbon storage that would have occurred anyway in the absence of the project.
Although most biomass carbon would be released before the project's permanence horizon, a small fraction may be stabilized permanently as soil carbon. This portion is counted as leakage and deducted from the project's carbon removal capacity.
The uncertainty around biomass carbon being 1) naturally incorporated into the soil and 2) converted to a stable carbon form is high, influenced by factors such as climate, soil type, soil health, and land use, making it hard to estimate for individual projects. Thus, it is assumed that a default 0.5% of the carbon in the biomass feedstock left on the soil, or reapplied to soil, will be permanently stored in soils.
Project Developers may conduct a project-specific assessment and provide a different carbon sequestration rate, but the final rate used in calculations shall be 0.5% or higher.
Biomass diversion and replacement
Leakage associated with the diversion and replacement of the biomass from its alternative use shall be quantified for each biomass used.
Project Developers shall follow the Alternative use and Biomass diversion and replacement guidelines in the Leakage section to determine the type and amount of replacement/substitute product or process.
Project Developers shall provide a conservative and representative emission factor for the production and use of the replacement product.
Biomass processing
The Rainbow Processing and energy use module shall be used to quantify the emissions from energy or material use for preparing biomass for pyrolysis. This includes but is not limited to drying and chipping biomass.
Transport of biomass and biochar
If biomass is transported to a pyrolysis site, or biochar is transported to its end-use point, using a vehicle that is not manually powered, transport emissions shall be accounted for using the Transportation module to calculate used in Eq. 2.
For this distributed small-scale technology type, it is expected that direct proof of transport will be unavailable (e.g., distance transported or fuel use during delivery). Therefore, Project Developers may provide justified and conservative estimates of transport distance, fuel consumed, and transport method.
Pyrolysis process
Any energy used to start the kiln (including high-quality wood and any associated leakage emissions), as well as energy used to combust methane emissions within the reactor, shall be included in the project’s total induced GHG emissions quantification. These emissions shall be calculated using the Processing and energy use module.
Methane emissions from pyrolysis shall be accounted for using direct methane measurements on a subset of representative kiln runs, following the Sampling and measurements requirements, and using the following equations.
Infrastructure and machinery
The Rainbow Infrastructure and machinery module shall be used to quantify the embodied emissions of kilns.
Biochar carbon storage
Project Developers shall choose between one of two approaches to quantify the gross carbon removals from their biochar product, as described in the Durability section. A single approach must be used consistently throughout each monitoring period, though a different approach may be chosen for subsequent monitoring periods.
Modeling 100-year removals using bulk measurements of , or
Estimating 1000-year removals using random reflectance measurements as proxies for inertinite.
Approach 1: Modeling 100-year removals using bulk measurements of
Project Developers shall quantify the gross carbon removals from their biochar project by modeling 100-year removals using bulk measurements of . These measurements shall be done once per Production Batch. The measurements shall be done on the Production Batch Representative Sample, mixing biochar from each kiln run. See Sampling and measurements for more details.
This approach is based on research from Woolf et al., 2021, and the IPCC modeling method. It is rooted in soil ecology and soil biochemistry disciplines. The permanent fraction of biochar carbon remaining after 100 years () is modeled according to the local average annual temperature.
Temperature shall be obtained in the following ways:
Biochar application to soil or mixing into horticultural products: Soil temperature shall be obtained for the end use location of each biochar spreading or mixing event, using the GPS coordinates provided in the Verification of end use report and the global soil temperature dataset from Lembrechts et al., 2021. The Rainbow Certification Team can provide soil temperature values for Project Developers based on the provided GPS coordinates.
Biochar mixing into concrete: Average annual air temperature at the location where biochar is mixed into concrete shall be used. It shall be taken from reputable public databases.
Table 2 Soil temperature ranges are categorized and their corresponding c and m regression coefficients are presented, which are used in Eq. 10 below to calculate . Values are taken from Woolf et al., 2021.
<7.49
1.13
0.46
7.5-12.49
1.10
0.59
12.5-17.49
1.04
0.64
17.5-22.49
1.01
0.65
>22.5
0.98
0.66
Approach 2: Estimating 1000-year removals based on inertinite fraction
This approach is based on the research from Sanei et al., 2024, and is rooted in the organic petrology and geochemistry disciplines. This approach is built upon research showing that fractions of inertinite in biochar samples are:
inert and permanent and will not re-release their carbon for at least 1000 years.
represented by the fraction of residual (i.e. not reactive, not labile) organic carbon in the sample with a Random Reflectance () of 2% or higher.
Project Developers shall provide distribution, labile organic carbon content, and moisture content for biochar from each Production Batch, following the Sampling requirements.
To determine the inertinite fraction of the biochar's organic carbon, first the labile carbon fraction is measured and subtracted from total organic carbon content, and only the residual organic carbon content is considered.
Next, random reflectance measurements are used to determine the fraction of residual organic carbon that is classified as inertinite:
The fraction of the distribution with an above 2% represents the fraction of the biochar carbon that is stored permanently for 1000 years.
The fraction of the distribution with an below 2% represents the fraction of biochar carbon that is not permanently stored, and for which no removal RCCs are issued.
distribution shall be based on at least 500 measurements, yielding a frequency distribution diagram similar to the examples in Figure 2a and 2b.


Uncertainty assessment
An uncertainty assessment is presented below for all aspects of GHG quantification set at the methodology level. The findings from this assessment are then applied at the project level, where project-specific GHG quantification also undergoes an uncertainty assessment.
The overall project GHG quantification uncertainty is determined by qualitatively combining both the methodology-level and project-specific uncertainties for each identified source of uncertainty.
The uncertainty of assumptions are assessed below:
All biochar from the same Production Batch has the same characteristics (e.g. , , inertinite content).
In principle this assumption has low uncertainty, but the ability of Kiln Operators to maintain consistent pyrolysis conditions across sites and across kiln runs is moderately uncertain.
All biochar made from the same feedstock has the same methane emission rate from pyrolysis.
In principle this assumption has low uncertainty, but the ability of Kiln Operators to maintain consistent pyrolysis conditions across sites and across kiln runs is moderately uncertain.
The permanent carbon sequestration rate from biomass leakage, where the alternate fate is being left on the field to decompose, is 0.5%.
High uncertainty, but the total net project removals is not sensitive to this assumption, so a low overall impact.
The equations and models have moderate uncertainty. The model for 100-year permanence from Woolf et al., 2021 has high uncertainty because it is a model fitted to experimental data, which always introduces variability. The equations for 1000-year permanence from Sanei et al., 2024 have low uncertainty because they are basic conversion equations.
Estimates may be used for the amount of processing and energy use inputs and the transport steps, rather than providing direct proof of each step. This is expected to introduce negligible to moderate uncertainty, depending on the level of justification provided for each project. For example, it may be negligible if the process is entirely manual/not motorized, requiring no transport or energy inputs. The uncertainty of these estimates and specific input data shall be assessed at the project level.
The uncertainty at the methodology level of the above-mentioned points are estimated to be moderate. This translates to a minimum discount factor of at least 6% for projects under this methodology.
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